Metal Enolates form a class of compounds that have recently received much study because of their part in the important C-C-bond forming aldol reaction. Focusing on this important class of compounds in organic synthesis, The Chemistry of Metal Enolates features contributions on all aspects of Metal Enolate chemistry from the world?s leading experts. Delivering the exceptional quality that?s expected from the Patai Series, this text is essential reading for organic chemists.
Inhaltsverzeichnis
1. General and theoretical aspects of the metal enolates
Luis R. Domingo and Juan Andrés
2. Molecular structure of metal enolates
Ksenija Babi?-Samard?ija, Sofija P. Sovilj and Vladislava M. Jovanovi?
3. Luminescence phenomena involving metal enolates
Hermi Felinto Brito, Oscar Manoel Loureiro Malta, Maria Claudia França Cunha Felinto and Ercules Epaminondas de Sousa Teotonio
4. Thermochemical considerations of metal enolates
Joel F. Liebman and Suzanne W. Slayden
5. Synthesis of metal enolato complexes
José Vicente
6. Coordination chemistry of metal enolato complexes
José Vicente
7. Metal enolates as synthons in organic chemistry
Daniel Stolz and Uli Kazmaier
8. Acid-base properties of enols and enolates
Jason Eames
9. Redox chemistry and electrochemistry of metal enolates
Guido Pampaloni and Piero Zanello
10. Catalysis using beta-diketonato metal complexes
Stephen A. Westcott
11. Biological aspects of metal enolates
Li-June Ming
12. Analytical aspects of metal enolates
Eli Harlev, Shmuel Bittner and Jacob Zabicky
13. The chemistry of metal ynolates
Mitsuru Shindo
14. Lanthanide enolates as nuclear magnetic resonance shift reagents
Thomas J. Wenzel and Katelyn A. Provencher
15. Metal enolates in polymer science and technology
Philippe Lecomte and Robert Jérôme
16. Structure and properties of d¯8 metal-dithiolene complexes
Paola Deplano, M. Laura Mercuri, Angela Serpe and Luca Pilia
17. Deposition of metals and metal oxides by means of metal enolates
Heinrich Lang and Roy Buschbeck
Author index
Subject index
Über den Autor
Jacob Zabicky is an emeritus professor at Ben Gurion University of the Negev in Beer Sheva, Israel. Earning his Ph.D. in Organic Chemistry with Saul Patai in the 1950s, he has since worked and taught at many different institutions in Israel, the UK, Venezuela, Germany, Spain, South Africa, and the USA. Prof. Zabicky is currently a lecturer at the Jerusalem College of Engineering and a member of the steering committee for the Israeli Center for Powder Technology. He has edited volumes in the Patai Series since the 1970s, the most recent ones on the subjects of metal enolates and metal phenolates.
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