Thanks to their excellent characteristics, epoxy resins belong to the most established binders within the coatings industry. This new book explains the basic principles of the chemistry of the epoxy group and imparts the use of epoxy and phenoxy resins in industrial coatings, such as anticorrosive coatings, floor coatings, powder coatings and can coatings, with the help of concrete formulations. Essential for any formulator of competitive modern paint systems!
Inhaltsverzeichnis
Content
1 Introduction, Michael Dornbusch
1.1 History
1.2 Application of epoxide resins
1.2.1 Coating agents
1.2.2 Construction materials
1.2.3 Adhesions
1.3 Terms and market
1.3.1 Nomenclature
1.3.2 Markets
1.4 Literature
2 Basic chemistry of the epoxy group, Michael Dornbusch
2.1 Properties and reactions of epoxy groups
2.1.1 Reaction with nucleophils
2.1.2 Reaction via acid catalyst
2.1.3 Properties of the epoxy group
2.2 Production and properties of epoxide resins
2.2.1 Production and properties of the monomers
2.2.1.1 Epichlorohydrin
2.2.1.2 Bisphenols
2.2.1.3 Epoxides based on olefins
2.2.1.4 Glycidyl ester
2.2.1.5 Aliphatic glycidyl ether
2.2.2 Production and propterties of the oligomers
2.2.2.1 Bisphenol based epoxide resins
2.2.2.2 Epoxide-novolaks
2.3 Parameters of epoxide resins
2.3.1 Epoxy equivalent of epoxy resins
2.3.2 OH-Number of epoxy resins
2.3.3 Chloride contents of epoxide resins
2.3.4 Investigation of the tendency to granulate of liquid resins
2.3.5 Detection reactions
2.4 Structure and properties of polymers based on epoxide resins and their curing
processes
2.4.1 Polyether polyol and phenoxy resins
2.4.2 Polyether polyol with epoxy groups
2.4.2.1 Catalytic curing of epoxide resins
2.4.3 Water based epoxide resins
2.4.4 Resins for hybrids with polymers based on epoxide resins
2.4.4.1 Epoxide acrylate
2.4.4.2 Epoxide alkyd, epoxyester
2.4.4.3 Epoxide-siloxane/silicone
2.4.4.4 Epoxide-polyamidimide
2.5 Literature
3 Epoxide in coatings
3.1 Epoxy groups as cross-linked building blocks, Michael Dornbusch
3.1.1 Overview of epoxy resins and hardeners
3.1.2 Epoxy groups in UV-curable coating systems
3.1.3 Epoxy groups in dip coatings
3.2 Protective coatings, Ulrich Christ
3.2.1 Industrial coatings
3.2.2 Corrosion protection
3.3 Applied flooring technology, Rob Rasing
3.3.1 Concrete
3.3.2 Application of epoxy thermosets for ambient cure condition
3.3.3 Floor design and installation
3.3.4 Industrial flooring performance attributes
3.3.5 High performance industrial flooring
3.4 Powder coatings, Ulrich Christ
3.4.1 Epoxy powder coatings
3.4.1.1 Curing with dicyandiamide (DICY)
3.4.1.2 Curing with phenolic resins
3.4.1.3 Curing with anhydrides
3.4.2 Epoxy polyester powder coatings or hybrid powder coatings
3.4.3 Polyester powder coatings
3.4.4 Acrylic powder coatings
3.5 Can and Coil Coatings, Michael Dornbusch
3.5.1 Can Coatings
3.5.2 Coil Coating
3.6 Literature
4 Trends and outlook, Ulrich Christ
4.1 Legal requirements related to health, safety and environmental protection
4.2 New product developments
4.2.1 Epoxy resins – applicable in future also for topcoats
4.2.2 New waterbased 1pack-epoxy technology for high duty corrosion protection systems
4.2.3 Improving the corrosion protection of 2pack- epoxy coatings by active anti-corrosion and barrier pigments
4.2.4 Trends in epoxy-based powder coatings
4.3 Potential replacement of BPA in Can Coatings, Michael Dornbusch
4.3.1 BPA replacement with bisphenol derivates
4.3.2 BPA replacement with new epoxide compounds
4.3.3 BPA replacement with other resins
4.4 Epoxides as building blocks for use of anthropogenic carbon dioxide for chemical syntheses, Ulrich Christ
4.5 Outlook – a strong growth predicted for epoxy resins
4.6 Literature
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