Explains the current state of the science and points the way
to technological advances
First developed in the late 1980s, lithium-ion batteries now
power everything from tablet computers to power tools to electric
cars. Despite tremendous progress in the last two decades in the
engineering and manufacturing of lithium-ion batteries, they are
currently unable to meet the energy and power demands of many new
and emerging devices. This book sets the stage for the development
of a new generation of higher-energy density, rechargeable
lithium-ion batteries by advancing battery chemistry and
identifying new electrode and electrolyte materials.
The first chapter of Lithium Batteries sets the
foundation for the rest of the book with a brief account of the
history of lithium-ion battery development. Next, the book covers
such topics as:
* Advanced organic and ionic liquid electrolytes for battery
applications
* Advanced cathode materials for lithium-ion batteries
* Metal fluorosulphates capable of doubling the energy density of
lithium-ion batteries
* Efforts to develop lithium-air batteries
* Alternative anode rechargeable batteries such as magnesium and
sodium anode systems
Each of the sixteen chapters has been contributed by one or more
leading experts in electrochemistry and lithium battery technology.
Their contributions are based on the latest published findings as
well as their own firsthand laboratory experience. Figures
throughout the book help readers understand the concepts underlying
the latest efforts to advance the science of batteries and develop
new materials. Readers will also find a bibliography at the end of
each chapter to facilitate further research into individual
topics.
Lithium Batteries provides electrochemistry students and
researchers with a snapshot of current efforts to improve battery
performance as well as the tools needed to advance their own
research efforts.
Tabla de materias
CONTRIBUTORS vii
PREFACE ix
CHAPTER 1 ELECTROCHEMICAL CELLS: BASICS 1
Hubert Gasteiger, Katharina Krischer, and Bruno Scrosati
CHAPTER 2 LITHIUM BATTERIES: FROM EARLY STAGES TO THE FUTURE
21
Bruno Scrosati
CHAPTER 3 ADDITIVES IN ORGANIC ELECTROLYTES FOR LITHIUM
BATTERIES 39
Susanne Wilken, Patrik Johansson, and Per Jacobsson
CHAPTER 4 ELECTROLYTES FOR LITHIUM-ION BATTERIES WITH
HIGH-VOLTAGE CATHODES 71
Mengqing Xu, Swapnil Dalavi, and Brett L. Lucht
CHAPTER 5 CORE-SHELL STRUCTURE CATHODE MATERIALS FOR
RECHARGEABLE LITHIUM BATTERIES 89
Seung-Taek Myung, Amine Khalil, and Yang-Kook Sun
CHAPTER 6 PROBLEMS AND EXPECTANCY IN LITHIUM BATTERY
TECHNOLOGIES 107
K. Kanamura
CHAPTER 7 FLUORINE-BASED POLYANIONIC COMPOUNDS FOR HIGH-VOLTAGE
ELECTRODE MATERIALS 127
P. Barpanda and J.-M. Tarascon
CHAPTER 8 LITHIUM-AIR AND OTHER BATTERIES BEYOND
LITHIUM-ION BATTERIES 161
K. M. Abraham
CHAPTER 9 AQUEOUS LITHIUM-AIR SYSTEMS 191
Owen Crowther and Mark Salomon
CHAPTER 10 POLYMER ELECTROLYTES FOR LITHIUM-AIR BATTERIES
217
Nobuyuki Imanishi and Osamu Yamamoto
CHAPTER 11 KINETICS OF THE OXYGEN ELECTRODE IN LITHIUM-AIR
CELLS 233
Michele Piana, Nikolaos Tsiouvaras, and Juan Herranz
CHAPTER 12 LITHIUM-ION BATTERIES AND SUPERCAPACITORS FOR USE IN
HYBRID ELECTRIC VEHICLES 265
Catia Arbizzani, Libero Damen, Mariachiara Lazzari, Francesca
Soavi, and Marina Mastragostino
CHAPTER 13 Li4Ti5O12 FOR HIGH-POWER, LONG-LIFE, AND SAFE
LITHIUM-ION BATTERIES 277
Zonghai Chen, I. Belharouak, Yang-Kook Sun, and Khalil
Amine
CHAPTER 14 SAFE LITHIIUM RECHARGEABLE BATTERIES BASED ON IONIC
LIQUIDS 291
A. Guerfi, A. Vijh, and K. Zaghib
CHAPTER 15 ELECTROLYTIC SOLUTIONS FOR RECHARGEABLE MAGNESIUM
BATTERIES 327
Y. Gofer, N. Pour, and D. Aurbach
CHAPTER 16 RECHARGEABLE SODIUM AND SODIUM-ION BATTERIES
349
K. M. Abraham
INDEX 369
Sobre el autor
BRUNO SCROSATI, Ph D, has been Professor of
Electrochemistry at the Sapienza University of Rome, and a visiting
professor at the Universities of Minnesota and Pennsylvania in the
U.S., and Hanyang University in South Korea. He is a past president
of the Electrochemical Society. He is a recipient of the Research
Award from the Battery Division of that society; the Vittorio de
Nora Award, also from the Electrochemical Society; and the XVI
Edition of the Italgas Prize, Science and Environment. He is the
author of more than 450 scientific publications.
K. M. ABRAHAM, Ph D, is Research Professor at Northeastern
University Center for Renewable Energy Technology, Boston, and the
principal of E-KEM Sciences. He has contributed pioneering work on
rechargeable lithium batteries and the invention of new lithium and
sodium battery chemical couples, including the ultrahigh-energy
density non-aqueous lithium-air battery. He is a Battery Research
Award winner and a Fellow of the Electrochemical Society.
WALTER VAN SCHALKWIJK, Ph D, is Principal at Energy Plex
Corporation and an Affiliate Professor of Chemical Engineering at
the University of Washington. With over thirty years of experience
in the battery industry, he is a member of the Electrochemical
Society, a past chairman of the society’s Nanotechnology Committee,
and a past member of its board of directors. He coedited
Advances in Lithium-Ion Batteries.
JUSEF HASSOUN, Ph D, is Assistant Research Scientist in
the Chemistry Department of the Sapienza University of Rome. He
obtained a Ph D in materials science in the field of advanced
lithium-ion batteries in 2009. He is author of more than sixty
papers in international journals in the fields of materials
science, electrochemistry, and energy storage systems.
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