Francesco Devillanova & Wolf-Walther Du Mont 
Handbook of Chalcogen Chemistry [PDF ebook] 
New Perspectives in Sulfur, Selenium and Tellurium Volume 2

The Handbook of Chalcogen Chemistry: New Perspectives in Sulfur, Selenium and Tellurium provides an overview of recent developments, particularly from the last decade, on the chemistry of the chalcogen group elements (S, Se and Te). While up to a few decades ago, chalcogen chemistry was mainly centred on sulphur, in recent years the research based on Se and Te has increased dramatically, and has created huge scope for the use of compounds based on this type of chemistry. The Handbook is organised into two parts, the first of which deals systematically with the chemistry of chalcogens in relation to other group elements in the periodic table. It also includes an overview of metal-chalcogenides and metal-polychalcogenides. The second part reflects the interdisciplinary nature of chalcogen chemistry and focuses on biological, materials and supramolecular aspects of the field. This Handbook gives a comprehensive overview on recent developments over the last decade and is ideal for researchers in the field.

Table des matières

Part 1; 1: Compounds containing the Boron-Chalcogen B-E (E = S, Se, Te) bond; 2: Compounds containing the Carbon-Chalcogen C-E (E = S, Se, Te) bond; 2.1: Thiolates, selenolates, and tellurolates; 2.2: Recent developments in the chemistry of thio-, seleno- and telluro-ethers; 2.3: Chalcogenone C=E compounds; 2.4: Thioamides, thioureas and related selenium and tellurium compounds; 3: Compounds containing the direct bond between Chalcogens and heavier group 14 Elements (Si, Ge, Sn); 4: Chalcogen-Nitrogen Chemistry; 5: Chalcogen-Phosphorus (and Heavier Congeners) Chemistry; 6: Chalcogen-Oxygen Chemistry; 7: Compounds containing the Chalcogen-Chalcogen E-E (E = S, Se, Te) bond; 7.1: Structure and bonding of the neutral chalcogens and their polyatomic cations; 7.2: Organochalcogen multication species; 8: Halogen-Chalcogen X-E (X = F, Cl, Br, I; E = S, Se, Te) Chemistry; 8.1: Recent developments in binary halogen-chalcogen compounds, polyanions and polycations; 8.2: C.T. Adducts and related compounds; 9: Metal Chalcogenides; 9.1: Metal-chalcogenides: clusters, layers, nanotubes; 9.2: Polychalcogenides; Part 2; 10: Miscellaneous Aspects; 10.1: Synthesis and stereochemistry of optically active chalcogen compounds; 10.2: 1, 1-Dithiolato ligands and related selenium and tellurium compounds; 10.3: Hypervalent chalcogen compounds; 11: Biological Chemistry; 11.1: Chalcogens (S, Se, Te) in microorganisms and plants; 11.2: Metal-sulfur clusters as model for the active sites of metalloenzimes; 12: Material Chemistry; 12.1: Stable chalcogen radicals; 12.2: Chalcogen reach compounds as electron donors; 12.3: 1, 2- Dithiolato ligands and related selenium and tellurium compounds; 13: Supramolecular Chemistry; 13.1: Chalgogen-halogen secondary bonds in self-assembling of supramolecular structures