Nitroxides are versatile small organic molecules possessing a stabilised free radical. With their unpaired electron spin they display a unique reactivity towards various environmental factors, enabling a diverse range of applications. They have uses as synthetic tools, such as catalysts or building blocks; imaging agents and probes in biomedicine and materials science; for medicinal antioxidant applications; and in energy storage. Polynitroxides (polymers bearing pendant nitroxide sidechains) have been used in organic radical batteries, oxidation catalysts and in exchange reactions for constructing complex architectures. Chapters in this book cover the synthesis of nitroxides, EPR studies and magnetic resonance applications, physiochemical studies, and applications including in batteries, imaging and organic synthesis. With contributions from leaders in the field, Nitroxides will be of interest to graduate students and researchers across chemistry, physics, biology and materials science.
Table des matières
A Brief History and Outlook of Nitroxides; General Approaches to Synthesis of Nitroxides; The Application of Nitroxides in Organic Synthesis; Sprin Probes and Imaging Using Nitroxides; Nitroxides in Battery-related Applications; Computational Tools for Nitroxide Design; Nitroxide-mediated Polymerization; Nitroxides in Supramolecular Chemistry; Magnetism of Nitroxides; Applications of Nitroxide Spin Labels to Structural Biology; Nitroxides in Liquid Crystals; Nitroxide Intervention in Oxidative and Free Radical Damage in Biology and Disease; Spin Trapping; Biological Applications of Nitroxide Stable Free Radicals; Introduction to Electron Paramagnetic Resonance (EPR) of Nitroxides
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