Aniline is the parent molecule of a vast family of aromatic amines.
Since its discovery in 1826 it has become one of the hundred most
important building blocks in chemistry. Aniline is used as an
intermediate in many different fields of applications, such as
isocyanates, rubber processing chemicals, dyes and pigments,
agricultural chemicals and pharmaceuticals.
The understanding of functional groups is key for the
understanding of all organic chemistry. In the tradition of the
Patai Series, this volume treats all aspects of this functional
group. It contains chapters on the theoretical and computational
foundations; on analytical and spectroscopical aspects with
dedicated chapters on Mass Spectrometry, NMR, IR/UV, etc.; on
reaction mechanisms; on applications in syntheses.
Table des matières
1 Anilines: Historical background (Anthony S. Travis).
2 General and theoretical aspects of anilines (Minh Tho
Nguyen).
3 Structural chemistry of anilines (Grazyna Maria
Wojcik).
4 Thermochemistry of anilines (Suzanne W. Slayden and Joel F.
Liebman).
5 Mass spectrometry and gas-phase chemistry of anilines
(Marcos N. Eberlin, Daniella Vasconcellos Augusti and
Rodinei Augusti).
6 NMR spectra of anilines (Erkki Kolehmainen, Ryszard
Gawinecki and Borys Osmialowski).
7 Substituted anilines as solvatochromic probes (Yizhak
Marcus).
8 Hydrogen bonds of anilines (Luciano Forlani).
9 Synthesis of anilines (John F. Hartwig, Shashank Shekhar,
Qilong Shen and Fabiola Barrios-Landeros).
10 Anilines as nucleophiles (Ikchoon Lee and Dae Dong
Sung).
11 Rearrangements of anilines and their derivatives (Sergei
M. Lukyanov and Alla V. Koblik).
12 Analytical aspects of aromatic amines (Jacob
Zabicky).
13 Manufacture and uses of the anilines: A vast array of
processes and products (Anthony S. Travis).
14 The spectroscopy, photophysics and photochemistry of anilines
(Jye-Shane Yang).
15 Toxicological and environmental aspects of anilines
(Anthony S. Travis).
16 Electrochemistry of anilines (Jan S. Jaworski and Marek K.
Kalinowski).
17 Proton sponges (Alexander F. Pozharskii and Valery A.
Ozeryanskii).
Author index.
Subject index.
A propos de l’auteur
Professor Zvi Rappoport, Department of Organic Chemistry, The Hebrew University of Jerusalem, Jerusalem, Israel.
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