Andre B. Charette 
Science of Synthesis: Houben-Weyl Methods of Molecular Transformations Vol. 22 [PDF ebook] 
Three Carbon-Heteroatom Bonds: Thio-, Seleno-, and Tellurocarboxylic Acids and Derivatives; Imidic Acids and Derivatives; Ortho Acid Derivatives

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Science of Synthesis: Houben-Weyl Methods of Molecular Transformations is the entirely new edition of the acclaimed reference series Houben-Weyl, the standard synthetic chemistry resource since 1909. This new edition is published in English and will comprise 48 volumes published between the years 2000 and 2008.

Science of Synthesis is a quality reference work developed by a highly esteemed editorial board to provide a comprehensive and critical selection of reliable organic and organometallic synthetic methods. This unique resource is designed to be the first point of reference when searching for a synthesis strategy.


  • Contains the expertise of presently 400 leading chemists worldwide

  • Critically evaluates the preparative applicability and significance of the synthetic methods

  • Discusses relevant background information and provides detailed experimental procedures


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<p>22 Introduction<br>22.1 Product Class 1: Thiocarboxylic Acids and Derivatives<br>22.1.1 Product Subclass 1: &alpha;-Substituted Sulfur Ylides<br>22.1.2 Product Subclass 2: Thioacyl Halides<br>22.1.3 Product Subclass 3: Thiocarboxylic <em>O</em>-Acid Esters<br>22.1.4 Product Subclass 4: Dithiocarboxylic Acid Esters<br>22.1.5 Product Subclass 5: Selenothiocarboxylic <em>Se</em>-Acid Esters<br>22.1.6 Product Subclass 6: Tellurothiocarboxylic <em>Te</em>-Acid Esters<br>22.1.7 Product Subclass 7: Thioamides<br>22.2 Product Class 2: Selenocarboxylic Acids and Derivatives<br>22.3 Product Class 3: Tellurocarboxylic Acids and Derivatives<br>22.4 Product Class 4: Imidic Acids and Derivatives<br>22.4.1 Product Subclass 1: Carbon-Substituted Iminium Salts<br>22.4.2 Product Subclass 2: <em>C</em>-Heteroatom-Substituted Nitrones, Other Dipoles<br>22.4.3 Product Subclass 3: Imidoyl (Imino) Halides<br>22.4.4 Product Subclass 4: Imidates<br>22.4.5 Product Subclass 5: Thioimidates and Their Derivatives<br>22.4.6 Product Subclass 6: Selenoimidates (Imidoselenoates) and Derivatives<br>22.4.7 Product Subclass 7: Telluroimidates (Imidotelluroates) and Derivatives<br>22.4.8 Product Subclass 8: <em>N</em>-Alkyl-, <em>N</em>-Aryl-, and <em>N</em>-Hetaryl-Substituted Amidines (Imidamides)<br>22.4.9 Product Subclass 9: Amidines (Imidamides) N-Substituted by Metals, Halogens, Oxygen, and Other Heteroatoms<br>22.5 Product Class 5: 2-Functionalized Alkylidenephosphines<br>22.6 Product Class 6: 2-Functionalized Arsaalkenes and &alpha;-Functionalized Arsonium Ylides<br>22.7 Product Class 7: Ortho Acid Derivatives<br>22.7.1 Product Subclass 1: Trihalomethyl Compounds<br>22.7.2 Product Subclass 2: Ortho Esters and Halogenated Derivatives<br>22.7.3 Product Subclass 3: Trithioortho Esters and Halogenated Derivatives<br>22.7.4 Product Subclass 4: Triselenoortho Esters and Halogenated Derivatives<br>22.7.5 Product Subclass 5: Tritelluroortho Esters and Halogenated Derivatives<br>22.7.6 Product Subclass 6: Ortho Amides (Alkane-1, 1, 1-triamines)<br>22.7.7 Product Subclass 7: Tris(diorganophosphino)methanes and Derivatives</p>

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