This book provides an introduction to the important methods of chiroptical spectroscopy in general, and circular dichroism (CD) in particular, which are increasingly important in all areas of chemistry, biochemistry, and structural biology. The book can be used as a text for undergraduate and graduate students and as a reference for researchers in academia and industry, with or without the companion volume in this set. Experimental methods and instrumentation are described with topics ranging from the most widely used methods (electronic and vibrational CD) to frontier areas such as nonlinear spectroscopy and photoelectron CD, as well as the theory of chiroptical methods and techniques for simulating chiroptical properties. Each chapter is written by one or more leading authorities with extensive experience in the field.
Daftar Isi
Comprehensive Chiroptical Spectroscopy, Volume 1
PREFACE ix
CONTRIBUTORS xi
PART I INTRODUCTION 1
1 ON THE INTERACTION OF LIGHT WITH MOLECULES: PATHWAYS TO THE
THEORETICAL INTERPRETATION OF CHIROPTICAL PHENOMENA 3
Georges H. Wagnière
PART II EXPERIMENTAL METHODSANDINSTRUMENTATION 35
2 MEASUREMENT OF THE CIRCULAR DICHROISM OF ELECTRONIC
TRANSITIONS 37
John C. Sutherland
3 CIRCULARLY POLARIZED LUMINESCENCE SPECTROSCOPY AND
EMISSION-DETECTED CIRCULAR DICHROISM 65
James P. Riehl and Gilles Muller
4 SOLID-STATE CHIROPTICAL SPECTROSCOPY: PRINCIPLES AND
APPLICATIONS 91
Reiko Kuroda and Takunori Harada
5 INFRARED VIBRATIONAL OPTICAL ACTIVITY: MEASUREMENT AND
INSTRUMENTATION 115
Laurence A. Nafie
6 MEASUREMENT OF RAMAN OPTICAL ACTIVITY 147
Werner Hug
7 NANOSECOND TIME-RESOLVED NATURAL AND MAGNETIC CHIROPTICAL
SPECTROSCOPIES 179
David S. Kliger, Eefei Chen, and Robert A. Goldbeck
8 FEMTOSECOND INFRARED CIRCULAR DICHROISM AND OPTICAL ROTATORY
DISPERSION 203
Hanju Rhee and Minhaeng Cho
9 CHIROPTICAL PROPERTIES OF LANTHANIDE COMPOUNDS IN AN EXTENDED
WAVELENGTH RANGE 221
Lorenzo Di Bari and Piero Salvadori
10 NEAR-INFRARED VIBRATIONAL CIRCULAR DICHROISM: NIR-VCD
247
Sergio Abbate, Giovanna Longhi, and Ettore Castiglioni
11 OPTICAL ROTATION AND INTRINSIC OPTICAL ACTIVITY 275
Patrick H. Vaccaro
12 CHIROPTICAL IMAGING OF CRYSTALS 325
John Freudenthal, Werner Kaminsky, and Bart Kahr
13 NONLINEAR OPTICAL SPECTROSCOPY OF CHIRAL MOLECULES 347
Peer Fischer
14 IN SITU MEASUREMENT OF CHIRALITY OF MOLECULES AND
MOLECULAR ASSEMBLIES WITH SURFACE NONLINEAR SPECTROSCOPY 373
Hong-fei Wang
15 PHOTOELECTRON CIRCULAR DICHROISM 407
Ivan Powis
16 MAGNETOCHIRAL DICHROISM AND BIREFRINGENCE 433
G. L. J. A. Rikken
17 X-RAY DETECTED OPTICAL ACTIVITY 457
Jose Goulon, Andrei Rogalev, and Christian Brouder
18 LINEAR DICHROISM 493
Alison Rodger
19 ELECTRO-OPTICAL ABSORPTION SPECTROSCOPY 525
Hans-Georg Kuball and Matthias Stolte
PART III THEORETICAL SIMULATIONS 541
20 INDEPENDENT SYSTEMS THEORY FOR PREDICTING ELECTRONIC CIRCULAR
DICHROISM 543
Gerhard Raabe, Joerg Fleischhauer, and Robert W. Woody
21 AB INITIO ELECTRONIC CIRCULAR DICHROISM AND OPTICAL
ROTATORY DISPERSION: FROM ORGANIC MOLECULES TO TRANSITION METAL
COMPLEXES 593
Jochen Autschbach
22 THEORETICAL ELECTRONIC CIRCULAR DICHROISM SPECTROSCOPY OF
LARGE ORGANIC AND SUPRAMOLECULAR SYSTEMS 643
Lars Goerigk, Holger Kruse, and Stefan Grimme
23 HIGH-ACCURACY QUANTUM CHEMISTRY AND CHIROPTICAL PROPERTIES
675
T. Daniel Crawford
24 AB INITIO METHODS FOR VIBRATIONAL CIRCULAR DICHROISM
AND RAMAN OPTICAL ACTIVITY 699
Kenneth Ruud
25 MODELING OF SOLVATION EFFECTS ON CHIROPTICAL SPECTRA
729
Magdalena Pecul
26 COMPLEXATION, SOLVATION, AND CHIRALITY TRANSFER IN
VIBRATIONAL CIRCULAR DICHROISM 747
Valentin Paul Nicu and Evert Jan Baerends
INDEX 783
Tentang Penulis
Nina Berova is a Research Professor in the Department of
Chemistry at Columbia University. She has been a coeditor of the
journal Chirality (Wiley) since 1998.
Prasad L. Polavarapu is currently a Professor of
Chemistry at Vanderbilt University.
Koji Nakanishi is one of the world’s leading natural
products chemists and was editor of the journal, The Chemical
Record (Wiley). He retired from Columbia University in 2007,
but continues to conduct research.
Robert W. Woody is an Emeritus Professor at Colorado
State University.
Ebook lainnya dari penulis yang sama / Editor
28,105 Ebooks dalam kategori ini
