Carbonyl and imino groups are two of the most integral functional groups employed in organic synthesis. Specific topics discussed: reduction, alkylation, alkenylation, and arylation of these groups, as well as asymmetric aldol, Mannich, and Morita-Bayliss-Hillman reactions.
This volume is part of a 3-volume set: Science of Synthesis Stereoselective Synthesis Workbench Edition
Further information about Stereoselective Synthesis (including sample pages and the table of contents)
Tabella dei contenuti
<p>2.1 Reduction of Carbonyl Groups: Hydrogenation<br>2.2 Reduction of Carbonyl Groups: Transfer Hydrogenation, Hydrosilylation, Catalytic Hydroboration, and Reduction with Borohydrides, Aluminum Hydrides, or Boranes<br>2.3 Enzymatic Reduction of Carbonyl Groups<br>2.4 Oxidative Deracemization<br>2.5 Stereoselective Reduction of Imino Groups<br>2.6 Epoxidation and Aziridination of Carbonyl Groups and Imines<br>2.7 Alkylation of Carbonyl and Imino Groups<br>2.8 Allylation of Carbonyl and Imino Groups<br>2.9 Arylation and Alkenylation of Carbonyl and Imino Groups<br>2.10.1 Enantioselective Addition of Acetylide Nucleophiles to Carbonyl Compounds<br>2.10.2 Enantioselective Addition of Metal Alkynylides to Imino Groups<br>2.11 Hydrocyanation, Cyanosilylation, and Hydrophosphonylation of Carbonyl and Imino Groups<br>2.12 Asymmetric Mukaiyama Aldol Reaction<br>2.13 Direct Aldol Reactions<br>2.14 Enzymatic Direct Aldol Additions<br>2.15 Asymmetric Morita–Baylis–Hillman Reaction and Its Aza Analogue<br>2.16 Mannich Reaction<br>2.17 Asymmetric Benzoin and Stetter Reactions<br>2.18 Asymmetric Synthesis of Spiroketals, Bisspiroketals, and Spiroaminals</p>
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