Molecular self-assembly is a widespread phenomenon in both chemistry and biochemistry. Yet it was not until the rise of supramolecular chemistry that attention has increasingly been given to the designed self-assembly of a variety of synthetic molecules and ions. To a large extent, success in this area has reflected knowledge gained from nature. However, an increased awareness of the latent steric and electronic information implanted in individual molecular components has also contributed to this success. Whilst not yet approaching the sophistication of biological assemblies, synthetic systems of increasing subtlety and considerable aesthetic appeal have been created. Self-Assembly in Supramolecular Systems surveys highlights of the progress made in the creation of discrete synthetic assemblies and provides a foundation for new workers in the area, as well as background reading for experienced supramolecular chemists.
Tabella dei contenuti
Self-assembly: What Does it Mean?; Intermolecular Interactions: The Glue of Supramolecular Chemistry; Hydrogen-bonded and π-Stacked Systems; Rotaxanes; Catenanes; Metal-directed Synthesis – Rotaxanes, Catenanes, Helicates and Knots; Further Metal-containing Systems; Subject Index.
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