Provides a unique summary of important catalytic reactions in the presence of silicon
A must-have for all synthetic chemists, this book summarizes all of the important developments in the application of organosilicon compounds in organic synthesis and catalysis. Edited by two world leaders in the field, it describes different approaches and covers a broad range of reactions, e.g. catalytic generation of silicon nucleophiles, Si-H Bond activation, C-H bond silylation, silicon-based cross-coupling reactions, and hydrosilylation in the presence of earth-abundant metals.
In addition to the topics covered above, Organosilicon Chemistry: Novel Approaches and Reactions features chapters that look at Lewis base activation of silicon Lewis acids, silylenes as ligands in catalysis, and chiral silicon molecules.
-The first book about this topic in decades, covering a broad range of reactions
-Covers new approaches and novel catalyst systems that have been developed in recent years
-Written by well-known, international experts in the areas of organometallic silicon chemistry and organosilicon cross-coupling reactions
Organosilicon Chemistry: Novel Approaches and Reactions is an indispensable source of information for synthetic chemists in academia and industry, working in the field of organic synthesis, catalysis, and main-group chemistry.
Tabella dei contenuti
1) Catalytic Generation of Silicon Nucleophiles
2) Si-H Bond Activation by Main-Group Lewis Acids
3) Si-H Bond Activation by Transition-Metal Lewis Acids
4) Metal-Ligand Cooperative Si-H Bond Activation
5) Cationic Silicon-Based Lewis Acids in Catalysis
6) Transition Metal-Catalyzed C-H Bond Silylation
7) Transition Metal-Free Catalytic C-H Bond Silylation
8) Silyl-Heck, Silyl-Negishi, and Related Reactions
9) Transition Metal-Catalyzed Cross-Coupling of Organosilicon Compounds
10) Lewis Base Activation of Silicon Lewis Acids
11) Hydrosilylation Catalyzed by Base Metals
12) Silylenes as Ligands in Catalysis
13) Enantioselective Synthesis of Silyl Ethers through Catalytic Si-O Bond Formation
14) Chiral Silicon Molecules
Circa l’autore
Tamejiro Hiyama, Ph D, is RDI Fellow at Chuo University and Professor Emeritus at Kyoto University (both in Japan). He is best known for his work in developing the Nozaki-Hiyama-Kishi reaction and the Hiyama cross-coupling. He is the recipient of the Chemical Society of Japan Award, the Humboldt Research Award, and the Frederic Stanley Kipping Award in Silicon Chemistry. He has published over 500 papers and 25 books.
Martin Oestreich, Ph D, is Einstein Professor of Synthesis and Catalysis at the Technische Universität Berlin, Germany. His research is focused on main-group chemistry related to catalysis with emphasis on silicon and boron. He is on the editorial advisory board of European Journal of Organic Chemistry, Chemical Society Reviews, and Chemical Science, and has published over 250 papers and five books.
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