This book is a comprehensive study of the subject of ionic
interactions in macromolecules. The first parts of the book review
and analyze the conventional treatments of fixed charges (e.g. in
polyelectrolytes and polyampholytes), including screening and
condensation by mobile ions. The interaction of ions with less
polar sites on the macromolecule (e.g. amide bonds), and the origin
of the lyotropic effects (focusing on binding versus condensation)
will also be extensively addressed.
The book also explores complex micellar organizations involving
charged macromolecules (e.g. DNA) and low-molecular-weight
ampholytes and strong protein associations. The resulting
structures are relevant to a variety of functional biological
systems and synthetic analogs. The contribution of electrostatic
and hydrophobic interaction to the stability of proteins and other
supramolecular structures will also be analyzed. There are chapters
on applications such as deionization and cosmetic formulation.
This 21-chapter book is divided into three sections:
* Fundamentals
* Mixed Interactions
* Functions and Applications
Spis treści
PREFACE ix
CONTRIBUTORS xiii
PART I FUNDAMENTALS 1
1 ION PROPERTIES 3
Yizhak Marcus
2 IONIC INTERACTIONS IN SUPRAMOLECULAR COMPLEXES 35
Hans-Jörg Schneider
3 POLYELECTROLYTE FUNDAMENTALS 49
Angelo Perico
4 POLYELECTROLYTE AND POLYAMPHOLYTE EFFECTS IN SYNTHETIC AND
BIOLOGICAL MACROMOLECULES 91
Ngo Minh Toan, Bae-Yeun Ha, and Dave Thirumalai
5 MODELING THE STRUCTURE AND DYNAMICS OF POLYELECTROLYTE
MULTILAYERS 121
Juan J. Cerdà, Christian Holm, and Baofu Qiao
PART II MIXED INTERACTIONS 167
6 IONIC MIXED INTERACTIONS AND HOFMEISTER EFFECTS 169
Alberto Ciferri
7 HYDROPHOBIC POLYELECTROLYTES 211
Andrés F. Olea
8 ASSOCIATION OF POLYELECTROLYTES TO SURFACTANTS AND
SUPRAMOLECULAR ASSEMBLIES: COMPETITIVE ROLE OF CHAIN RIGIDITY AND
ASSEMBLY STABILITY 235
Alberto Ciferri and Angelo Perico
9 ION TRANSFER IN AND THROUGH CHARGED MEMBRANES: STRUCTURE,
PROPERTIES, AND THEORY 267
Victor V. Nikonenko, Andrey B. Yaroslavtsev, and Gérald
Pourcelly
10 REVERSIBLE COORDINATION POLYMERS 337
Kim de Lange, Jos M.J. Paulusse, Antonius T.M. Marcelis, and Han
Zuilhof
11 STRUCTURAL AND FUNCTIONAL ASPECTS OF METAL BINDING SITES IN
NATURAL AND DESIGNED METALLOPROTEINS 361
Ornella Maglio, Flavia Nastri, and Angela Lombardi
12 CHARGE-INDUCED EFFECTS ON ACID-BASE TITRATION AND
CONFORMATIONAL STABILITY OF PROTEINS AND POLYPEPTIDES 451
Jan Hermans
PART III FUNCTIONS AND APPLICATIONS 483
13 IRON TRANSPORT IN LIVING CELLS 485
Alvin L. Crumbliss and Claire J. Parker Siburt
14 DNA-LIPID AMPHIPHILES FOR DRUG AND GENE THERAPY 551
Peggy P.Y. Chan and Li Shan Wang
15 POLYELECTROLYTE INTELLIGENT GELS: DESIGN AND APPLICATIONS
581
Piero Chiarelli and Danilo De Rossi
16 IONIC POLYMER-METAL COMPOSITES FOR SENSORS AND
ARTIFICIAL MUSCLES: MECHANOELECTRIC PERSPECTIVES 621
Rashi Tiwari and Kwang J. Kim
17 FUNCTIONAL LAYER-BY-LAYER POLYELECTROLYTES: ASSEMBLY
STRATEGIES, CHARACTERIZATION, AND SELECTED APPLICATIONS 643
Nicel Estillore, Wolfgang Knoll, and Rigoberto Advincula
18 POLYELECTROLYTES AT INTERFACES: APPLICATIONS AND TRANSPORT
PROPERTIES OF POLYELECTROLYTE MULTILAYERS IN MEMBRANES 683
Bastien Seantier and André Deratani
19 SELF-ASSEMBLY OF POLYELECTROLYTES FOR PHOTONIC CRYSTAL
APPLICATIONS 727
Dario Cavallo and Davide Comoretto
20 APPLICATIONS OF CHARGED MEMBRANES IN SEPARATION, FUEL CELLS,
AND EMERGING PROCESSES 761
Gérald Pourcelly, Victor V. Nikonenko, Natalia D.
Pismenskaya, and Andrey B. Yaroslavtsev
21 POLYMER GEL ELECTROLYTES: CONDUCTION MECHANISM AND BATTERY
APPLICATIONS 817
Ian M. Ward and Hugh V. St. A. Hubbard
LIST OF SYMBOLS 841
INDEX 843
O autorze
Alberto Ciferri is currently a Visiting Professor at Duke
University, an Associate at the National Research Council (ISMAC),
and President of the Jepa-Limmat Foundation, which is devoted to
advanced education in developing countries. His research has had
significant impact in the areas of the rheological properties of
natural and synthetic polymers, fibrous proteins, interactions
between salts and macromolecules, liquid crystals, and
supramolecular assemblies.
Angelo Perico is Research Director at the National Research
Council, associated with the Institute for Macromolecular Studies,
in Genoa, Italy. Dr. Perico’s research is related to theory and
modeling of synthetic and biological macromolecules and their
dynamics, assembly, and functions, particularly the interactions
among oppositely and similarly charged polyelectrolytes and on the
electrostatic effects that promote the formation of complex
biomolecular structures.
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