an integrated approach to electron transfer phenomena
This two-part stand-alone volume in the prestigious Advances in
Chemical Physics series provides the most comprehensive overview of
electron transfer science today. It draws on cutting-edge research
from diverse areas of chemistry, physics, and biology-covering the
most recent developments in the field, and pointing to important
future trends. This second volume offers the following
sections:
* Solvent control, including ultrafast solvation dynamics and
related topics
* Ultrafast electron transfer and coherence effects
* Molecular electronics
* Electron transfer and exciplex chemistry
* Biomolecules-from electron transfer tubes to kinetics in a DNA
environment
Part One addresses the historical perspective, electron transfer
phenomena in isolated molecules and clusters, general theory, and
electron transfer kinetics in bridged compounds.
Electron transfer science has seen tremendous progress in recent
years. Technological innovations, most notably the advent of
femtosecond lasers, now permit the real-time investigation of
intramolecular and intermolecular electron transfer processes on a
time scale of nuclear motion. New scientific information abounds,
illuminating the processes of energy acquisition, storage, and
disposal in large molecules, clusters, condensed phase, and
biophysical systems.
Electron Transfer: From Isolated Molecules to Biomolecules is the
first book devoted to the exciting work being done in nonradiative
electron transfer dynamics today. This two-part edited volume
emphasizes the interdisciplinary nature of the field, bringing
together the contributions of pioneers in chemistry, physics, and
biology. Both theoretical and experimental topics are featured. The
authors describe modern approaches to the exploration of different
systems, including supersonic beam techniques, femtosecond laser
spectroscopy, chemical syntheses, and methods in genetic and
chemical engineering. They examine applications in such areas as
supersonic jets, solvents, electrodes, semi- conductors,
respiratory and enzymatic protein systems, photosynthesis, and
more. They also relate electron transfer and radiationless
transitions theory to pertinent physical phenomena, and provide a
conceptual framework for the different processes.
Complete with over two hundred illustrations, Part Two opens with
solvent control issues, including electron transfer reactions and
ultrafast solvation dynamics. Other topics include ultrafast
electron transfer and coherence effects, molecular electronics, and
electron transfer in exciplex chemistry. This volume concludes with
a section on biomolecules-from electron transfer tubes to
experimental electron transfer and transport in DNA.
Timely, comprehensive, and authoritative, Electron Transfer: From
Isolated Molecules to Biomolecules is an essential resource for
physical chemists, molecular physicists, and researchers working in
nonradiative dynamics today.
Spis treści
Interplay Between Ultrafast Polar Solvation and Vibrational
Dynamics in Electron Transfer Reactions: Role of High-Frequency
Vibrational Modes (B. Bagchi & N. Gayathri).
Solvent Control of Electron Transfer Reactions (F. Raineri & H.
Friedman).
Theoretical and Experimental Study of Ultrafast Solvation Dynamics
by Transient Four-Photon Spectroscopy (B. Fainberg & D.
Huppert).
Coherence and Adiabaticity in Ultrafast Electron Transfer (K. Wynne
& R. Hochstrasser).
Electron Transfer and Solvent Dynamics in Two- and Three-State
Systems (M. Cho & G. Fleming).
Ultrafast Intermolecular Electron Transfer in Solution (K.
Yoshihara).
Electron Transfer in Molecules and Molecular Wires: Geometry
Dependence, Coherent Transfer, and Control (V. Mujica, et
al.).
Electron Transfer and Exciplex Chemistry (N. Mataga & H.
Miyasaka).
Electron-Transfer Tubes (J. Regan & J. Onuchic).
Copper Proteins as Model Systems for Investigating Intramolecular
Electron Transfer Processes (O. Farver & I. Pecht).
Applying Marcus’s Theory to Electron Transfer in Vivo (G. Mc Lendon,
et al.).
Solvent-Fluctuation Control of Solution Reactions and Its
Manifestation in Protein Functions (H. Sumi).
Experimental Electron Transfer Kinetics in a DNA Environment (P.
Barbara & E. Olson).
Indexes.
O autorze
JOSHUA JORTNER is Heinemann Professor of Chemistry at Tel Aviv
University’s School of Chemistry, where he has been on the faculty
since 1964. Professor Jortner is President of the International
Union of Pure and Applied Chemistry, former President of the Israel
National Academy of Sciences and Humanities, and the recipient of
the Wolf Prize in Chemistry (1988).
M. BIXON is Chemistry Professor at Tel Aviv University’s School of
Chemistry, where he has been on the faculty since 1966. He holds a
Ph D from the Weizmann Institute of Science in Rehovot, Israel.
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