Fundamental Aspects of Plasma Chemical Physics – Thermodynamics develops basic and advanced concepts of plasma thermodynamics from both classical and statistical points of view.
After a refreshment of classical thermodynamics applied to the dissociation and ionization regimes, the book invites the reader to discover the role of electronic excitation in affecting the properties of plasmas, a topic often overlooked by the thermal plasma community.
Particular attention is devoted to the problem of the divergence of the partition function of atomic species and the state-to-state approach for calculating the partition function of diatomic and polyatomic molecules. The limit of ideal gas approximation is also discussed, by introducing Debye-Huckel and virial corrections.
Throughout the book, worked examples are given in order to clarify concepts and mathematical approaches.
This book is a first of a series of three books to be published by the authors on fundamental aspects of plasma chemical physics. The next books will discuss transport and kinetics.
Spis treści
Classical Thermodynamics.- Two and Three Level Systems.- Statistical Thermodynamics.- Atomic Partition Function.- Molecular Partition Function.- Real Effects: I. Debye-Hückel.- Real Effects: II. Virial Corrections.- Electronic Excitation.- Multi-Temperature Thermodynamics.- Thermodynamics of Planetary Plasmas.- Appendix.
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