It is a basic law of chemistry that pressure influences reactions. Thus, high-pressure reactions are no longer a rarity in chemistry today, but rather are indispensable tools – whether for innovative syntheses, new products or for explaining reaction mechanisms.
The expert editors, Rudi van Eldik and Frank-Gerrit Klarner, provide a comprehensive overview of this fascinating field, ranging from the influence of high pressure on organic and inorganic reactions, via concrete applications in synthesis for metal catalytic and stereoselective processes right up to the use of supercritical liquids.
Written by renowned experts, this volume contains a wealth of vital and practical information, for both newcomers to the field as well as experienced high-pressure chemists. Whether in academia or industry, this book belongs on the shelf of every chemist concerned with high-pressure chemistry either now or in the future.
Tabela de Conteúdo
BASIC PRINCIPLES.
Effect of Pressure on Inorganic and Metalorganic Reactions : Introduction and Mechanistic Applications (R. van Eldik and C.D. Hubbard).
The Effect of Pressure on Organic Reactions: Basic Principles and Mechanistic Applications (F. Wurche and F-G Klärner).
High-Pressure Kinetics and Highly Viscous Media (T. Asano).
MECHANISTIC AND SYNTHETIC APPLICATIONS OF HIGH PRESSURE.
Water Exchange on Metal Ions: The Effect of Pressure (L. Helm and A.E. Merbach).
Insights into Solution Chemistry from High Pressure Electrochemistry (T.W. Swaddle).
Pressure Effects on the Phtoreactions of Transition Metal Complexes (P.C. Ford and L.E. Laverman).
Application of High Pressure Transition Metal-Catalyzed Reactions (O. Reiser).
High Pressure in Organic Synthesis: Influence on Selectivity (L.F. Tietze and P.L. Steck).
High-Pressure Promoted Cycloadditions for Application in Combinatorial Chemistry (G.J.T. Kuster and H.W. Scheeren).
Catalytic and Solvophobic Promotion of High Pressure Addition Reactions (G. Jenner).
Future Perspectives: Applications of High Pressure in Supramolecular Chemistry (R. Ruloff, et al.).
CHEMICAL REACTIONS IN SUPERCRITICAL FLUIDS.
Catalytic Reactions in Supercritical Fluids (J. Hyde, et al.).
Application of Supercritical Fluids in the Fine Chemical Industry (W. Bonrath and R. Karge).
Applications of Supercritical Water (E. Dinjus and A.Kruse).
Index.
Sobre o autor
Rudi van Eldik, DSc, is Professor of Inorganic Chemistry at the University of Erlangen-Nurnberg, Germany. He is the editor of Inorganic High Pressure Chemistry and coeditor of High Pressure Chemistry and Biochemistry.
Frank-Gerrit Klärner is the editor of High Pressure Chemistry: Synthetic, Mechanistic, and Supercritical Applications, published by Wiley.
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