M Green 
Organometallic Chemistry [PDF ebook] 
Volume 33

Groups 1 and 11: The Alkali and Coinage Metals; 1 Alkali Metals; 1.1 Introduction; 1.2 Alkyl Derivatives; 1.3 Alkenyl, Allyl, Vinyl, Alkynyl and Related Derivatives; 1.4 Aryl Derivatives; 1.5 Cyclopentadienyl and Related Derivatives; 2 Copper, Silver and Gold; 2.1 Introduction; 2.2 Copper Compounds; 2.3 Silver Compounds; 2.4 Gold Compounds; References; Group 2 (Be-Ba) and Group 12 (Zn-Hg); 1 Scope and Organisation of the Review; 2 Group 2; 3 Group 12; References; Scandium, Yttrium and the Lanthanides; 1 Introduction; 2 Hydrocarbyls of Various Kinds; 3 Half Sandwich Cyclopentadienyl Complexes; 4 Metallocene Derivatives; 5 Ansa Metallocene Ligand Chemistry; 6 Indenyl and Fluorenyl Complexes; 7 Functionalized Cyclopentadienyls and Related Ligands; 7.1 Functional Groups with Nitrogen Donors; 7.2 Functional Groups with Group 16 Donors; 8 Hydride Complexes; 9 Allyls; 10 Cyclo-Octatetraenyl Complexes; 11 Nitrogen-Donor Ancillaries; 11.1 Ketiminate Chemistry; 11.2 Amido Ancillary Groups; 12 Organophosphorus Supporting Ligands; 13 Aryloxide Ancillaries; 14 Compounds with Boron-Based Ligands; 15 Materials Chemistry; 16 Applications in Organic Synthesis; 16.1 Stoichiometric Reactions; 16.2 Catalysis; 17 Polymerization Catalysis; 17.1 Neutral Olefins and Dienes; 17.2 Acrylate and Polar Monomer Polymerization; 18 Theoretical and Computational Studies; 18.1 Structure and Bonding; 18.3 Agostic Interactions; 18.4 Interaction of Small Molecules; 18.5 Calculating Chemical Reactivity; 18.6 Pretend Molecules; 19 Spectroscopic Studies; References; Carboranes, Including Their Metal Complexes; 1 Introduction; 2 Theoretical and Computational Studies; 3 Heteroboranes, Carboranes and Heterocarboranes; 3.1 {B3 and B4}; 3.2 {B8, B9 and B10}; 3.3 {B12}; 3.4 {PCB8}; 3.5 {SB8}; 3.6 {CB6, CB7, CB8, CB9}; 3.7 {CB11}; 3.8 {NC2B7}; 3.9 {As2C2B7}; 3.10 {C2B9}; 3.11 {C2B10}; 3.12 {C2B11}; 4 Metallaboranes and Metallacarboranes; 4.1 {MB3 and MB4}; 4.2 {MB5}; 4.3 {MB6 and MB8}; 4.4 {MCB8}; 4.5 {MCB9}; 4.6 {MCB10}; 4.7 {MC2B4}; 4.8 {C2B8}; 4.9 {MC2B9}; 4.10 {MC2B10}; 4.11 {MPC2B8}; 4.12 {M2C3B8}; 4.13 {exo-C2B9}; 5 Biological Carborane Chemistry and BNCT; 6 Weakly Coordinating Anions and Catalysis; 7 Crystal Engineered Supramolecular and Polymeric (Metalla)carborane Materials; References; Group III — B, Al, Ga, In, Tll; 1 General; 2 Boron; 2.1 B(C6F5)3 and Related Boranes; 2.2 Borate Anions; 2.3 Ligand Systems Based Around a Tri- or Tetra-Coordinate Boron Centre; 2.4 Boron Hydrides; 2.5 Boron-Based Ligand Systems; 2.6 Boratabenzenes and Related Systems; 2.7 Boron-Containing Materials and Sensors; 2.8 Boronic Acids/Esters and Suzuki Type Coupling Reactions; 2.9 Boron Functionalized Cyclopentadienyl Ligands; 2.10 Miscellaneous; 3 Aluminium; 3.1 Hydrides; 3.2 Aluminate Complexes; 3.3 Aluminium Derivatives Containing Bonds to Group 15 Donors; 3.4 Aluminium Derivatives Containing Bonds to Oxygen; 3.5 Aluminium Organometallics in Organic Synthesis; 3.6 Miscellaneous Examples; 4 Gallium; 4.1 Subvalent Gallium Species and Clusters; 4.2 Complexes Containing Subvalent Gallium Species as Ligands; 4.3 Arylgallium Species; 4.4 Gallium Hydrides; 4.5 Gallium Derivatives Containing Bonds to Group 15 or Group 16 Elements; 4.6 Miscellaneous; 5 Indium; 5.1 Subvalent Indium and Indium Clusters; 5.2 Indium Derivatives Containing Bonds to Groups 15 or 16; 5.3 Miscellaneous Examples; 6 Thallium; References; Group 14: Silicon, Germanium, Tin and Lead; 1 Overview; 2 Multiple Bonds in Group 14; 3 Tetrylenes; 4 Radicals, Cations and Anions; 5 Homoaromatics and Other Ring Systems; 6 Pi-Bonded Complexes; 7 Group 14 Organometallics as Ligands at Transition Metal Centres; References; Recent Advances in the Chemistry of Phosphaalkynes: Building Blocks for Novel Organophosphorus Compounds; 1 Introduction; 2 Synthesis of New Phosphaalkynes; 3 Phosphagrignard Reagents and Related Compounds; 4 Synthesis of Four-Membered Rings; 5 Synthesis of Higher Phosphaalkyne Oligomers; 6 Synthesis of Cluster Compounds; 7 Conclusions and Outlook; References; Organo-Transition Metal Cluster Complexes; Abbreviations; 1 Introduction; 2 General Reviews; 3 Spectroscopic Studies; 4 Theory; 5 Structural Studies; 6 High-Nuclearity Clusters; 6.1 Homonuclear High-Nuclearity Clusters; 6.2 Heteronuclear High-Nuclearity Clusters; 7 Group 6; 8 Group 7; 9 Group 8; 9.1 Iron; 9.2 Ruthenium; 9.3 Osmium; 9.4 Mixed-Metal Clusters Containing Only Group 8 Metals; 9.5 Group 8 Clusters in Catalysis; 10 Group 9; 10.1 Cobalt; 10.2 Rhodium; 10.3 Iridium; 10.4 Group 9 Mixed-Metal Clusters; 11 Group 10; 12 Group 11; 13 Mixed-Metal Clusters; 13.1 Group 5; 13.2 Group 6; 13.3 Group 7; 13.4 Group 8; 13.5 Group 9; 13.6 Group 10; 13.7 Clusters Containing Three Different Metals; References; Complexes Containing Metal-Carbon r-Bonds of the Groups Iron, Cobalt and Nickel, Including Carbenes and Carbynes; 1 Introduction; 2 Reviews and Articles of General Interest; 3 Metal-Carbon s-Bonds Involving Group 8, 9 and 10 Metals; 3.1 The Iron Triad; 3.2 The Cobalt Triad; 3.3 The Nickel Triad; 4 Carbene and Carbyne Complexes of Group 8, 9 and 10; References; Organic Aspects of Organometallic Chemistry; 1 Introduction; 2 Methods for C-C Bond Formation; 3 Methods for C-X Bond Formation; 4 Metal Mediated Cyclisation and Cycloisomerisation Reactions; 5 Nicholas and Pauson-Khand Type Reactions; References;