Praise for the previous editions
‘An excellent text . . . will no doubt provide the benchmark for
comparative works for many years.’ –Journal of the
American Chemical Society
‘An excellent state-of-the-art compilation of catalytic
asymmetric chemistry . . . should be included in any chemistry
reference collection.’ –Choice
‘This is a tremendous resource and an excellent read. I
recommend immediate purchase.’ –Perkin
Transactions
Since this important work was first published in 1993, the field
of catalytic asymmetric synthesis has grown explosively, spawning
effective new methods for obtaining enantiomerically pure compounds
on a large scale and stimulating new applications in diverse
fields–from medicine to materials science. Catalytic
Asymmetric Synthesis, Third Edition addresses these rapid
changes through contributions from highly recognized world leaders
in the field.
This seminal text presents detailed accounts of the most
important catalytic asymmetric reactions known today, and discusses
recent advances and essential information on the initial
development of certain processes. An excellent working resource for
academic researchers and industrial chemists alike, the Third
Edition features:
* Six entirely new chapters focusing on novel approaches to
catalytic asymmetric synthesis including non-conventional
media/conditions, organocatalysis, chiral Lewis and Bronsted acids,
CH activation, carbon-heteroatom bond-forming reactions, and
enzyme-catalyzed asymmetric synthesis
* A new section focusing on the important new reaction, asymmetric
metathesis, in carbon-carbon bond-forming reactions
* Updated chapters on hydrogenation, carbon-carbon bond-forming
reactions, hydrosilylations, carbonylations, oxidations,
amplifications and autocatalysis, and polymerization reactions
Retaining the best of its predecessors but now thoroughly up to
date, Catalytic Asymmetric Synthesis, Third Edition serves
as an excellent desktop reference and text for researchers and
students from the upper-level undergraduates through experienced
professionals in industry or academia.
สารบัญ
Preface ix
Preface to the Second Edition xi
Preface to the First Edition xiii
Contributors xv
1 Catalytic Asymmetric Synthesis in Nonconventional Media/Conditions 1
Chikako Ogawa and Shu Kobayashi
2 Asymmetric Organocatalysis 37
2A Enantioselective Organocatalysis Involving Iminium, Enamine, SOMO, and Photoredox Activation 39
Allan J. B. Watson and David W. C. Mac Millan
2B Asymmetric Acid-Base Bifunctional Catalysis with Organic Molecules 59
Yi Wang and Li Deng
2C Asymmetric Phase-Transfer and Ion Pair Catalysis 95
Seiji Shirakawa and Keiji Maruoka
3 Chiral Lewis Acids and Brønsted Acids in Asymmetric Synthesis 119
Hisashi Yamamoto and Cheol Hong Cheon
4 Asymmetric Synthesis through C-H Activation 163
Huw M. L. Davies and Jørn Hansen
5 Asymmetric Carbon-Heteroatom Bond-Forming Reactions 227
Yoshiji Takemoto and Hideto Miyabe
6 Enzyme-Catalyzed Asymmetric Synthesis 269
Harald Gröger
7 Transition Metal-Catalyzed Homogeneous Asymmetric Hydrogenation 343
Gao Shang, Wei Li, and Xumu Zhang
8 Asymmetric Carbon-Carbon Bond-Forming Reactions 437
8A Catalytic Asymmetric Conjugate Addition 439
Jian-Xin Ji and Albert S. C. Chan
8B Enantioselective Allylic Substitutions with Carbon Nucleophiles 497
Günter Helmchen, Uli Kazmaier, and Sebastian Förster
8C Asymmetric Carbometallation and Carbocyclizations 643
Iwao Ojima, Joseph J. Kaloko, Stephen J. Chaterpaul, Yu-Han Gary Teng, and Chi-Feng Lin
8D Asymmetric Ene Reactions and Cycloadditions 683
Koichi Mikami and Kohsuke Aikawa
8E Catalytic Enantioselective Olefin Metathesis Reactions 739
Amir H. Hoveyda, Steven J. Malcolmson, Simon J. Meek, and Adil R. Zhugralin
9 Asymmetric Hydrosilylation of Carbon-Carbon Double Bonds and Related Reactions 771
Jin Wook Han and Tamio Hayashi
10 Asymmetric Carbonylations 799
Cyril Godard, Aurora Ruiz, Montserrat Diéguez, Oscar Pàmies, and Carmen Claver
11 Asymmetric Oxidations and Related Reactions 839
Kazuhiro Matsumoto and Tsutomu Katsuki
12 Asymmetric Amplification and Autocatalysis 891
Kenso Soai, Tsuneomi Kawasaki, and Takanori Shibata
13 Asymmetric Polymerization 931
Shingo Ito and Kyoko Nozaki
Index 987
เกี่ยวกับผู้แต่ง
IWAO OJIMA, Ph D, a world-renowned leader in asymmetric catalysis, medicinal chemistry, and drug discovery, is the Distinguished Professor of Chemistry and the Director of the Institute of Chemical Biology and Drug Discovery at the State University of New York at Stony Brook. He is a recipient of numerous awards, including the Arthur C. Cope Scholar Award (ACS), the Chemical Society of Japan Award, and the E. B. Hershberg Award (ACS). He is a Fellow of the Guggenheim Foundation, the American Association for the Advancement of Science, and the New York Academy of Sciences. Dr. Ojima was inducted to the Medicinal Chemistry Hall of Fame (ACS) in 2006.
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