Shu Kobayashi 
Science of Synthesis: Water in Organic Synthesis [EPUB ebook] 

<p>1 Introduction<br>2 Structure and Properties of Water<br>3 Aqueous Media: Reactions of C&#8212;C Multiple Bonds<br>3.1 Asymmetric Oxidation Reactions: Sulfoxidation, Epoxidation, Dihydroxylation, and Aminohydroxylation<br>3.2 Hydrogenation of Alkenes, Alkynes, Arenes, and Hetarenes<br>3.3 Hydroformylation and Related Reactions<br>3.4 Conjugate Addition Reactions<br>3.5 Cyclopropanation Reactions<br>3.6 Metathesis Reactions<br>4 Aqueous Media: Reactions of Carbonyl and Imino Groups<br>4.1 Reduction of Carbonyl and Imino Groups<br>4.2 Alkylation, Allylation, and Benzylation of Carbonyl and Imino Groups<br>4.3 Arylation, Vinylation, and Alkynylation of Carbonyl and Imino Groups<br>4.4 Aldol Reaction<br>4.5 Mannich Reaction and Baylis&#8211;Hillman Reaction<br>5 Aqueous Media: Cyclization, Rearrangement, Substitution, Cross Coupling, Oxidation, and Other Reactions<br>5.1 Cycloaddition and Cyclization Reactions<br>5.2 Pericyclic Rearrangements: Sigmatropic, Electrocyclic, and Ene Reactions<br>5.3 Allylic and Aromatic Substitution Reactions<br>5.4 Cross-Coupling and Heck Reactions<br>5.5 Ring Opening of Epoxides and Aziridines<br>5.6 Asymmetric &alpha;-Functionalization of Carbonyl Compounds and Alkylation of Enolates<br>5.7 Oxidation of Alcohols, Allylic and Benzylic Oxidation, Oxidation of Sulfides<br>5.8 Free-Radical Reactions<br>5.9 Polymerization<br>6 Special Techniques with Water<br>6.1 Organic Synthesis ‘On Water'<br>6.2 Sub- and Supercritical Water<br>6.3 &beta;-Cyclodextrin Chemistry in Water<br>7 Industrial Application<br>7.1 Hydroformylation<br>7.2 Industrial Applications Other than Hydroformylation<br>8 Perspective: The New World of Organic Chemistry Using Water as Solvent</p>