Magnesium remains almost unique among the metals in its ability to react directly with a wide variety of compounds. This organic chemistry field has seen steady progress, and a volume on this topic is long overdue. In the tradition of the Patai Series this title treats all aspects of functional groups, containing chapters on the theoretical and computational foundations; on analytical and spectroscopic aspects with dedicated chapters on Mass Spectrometry, NMR, IR/UV, etc.; on reaction mechanisms; on applications in syntheses. Depending on the functional group there are also chapters on industrial use, on effects in biological and/or environmental systems. Since the area of Organomagnesium Chemistry continues to grow far beyond the classical Grignard Reagents, this is an essential resource to help the reader keep abreast of the latest developments.
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1. Structural organomagnesium chemistry (Johann T.B.H. Jastrzebski,
Jaap Boersma and Gerard van Koten).
2. The thermochemistry of organomagnesium compounds (Joel F.
Liebman, Torkil Holm and Suzanne W. Slayden).
3. NMR of organomagnesium compounds (Peter J. Heard).
4. Formation, chemistry and structure of organomagnesium species
in solvent-free environments (Richard A. J. O’Hair).
5. Photochemical transformations involving magnesium porphyrins
and phthalocyanines (Natalia N. Sergeeva and Mathias O. Senge).
6. Electrochemistry of organomagnesium compounds (Jan S.
Jaworski).
7. Analytical aspects of organomagnesium compounds (Jacob
Zabicky).
8. Biochemistry of magnesium (James Weston).
9. Theoretical studies of the addition of RMg X to carbonyl
compounds (Shinichi Yamabe and Shoko Yamazaki).
10. Organomagnesium-group 15-and Organomagnesium-group 16-bonded
complexes (Katherine L. Hull and Kenneth W. Henderson).
11. Preparation and reactivity of Magnesium enolates (Claude
Grison).
12. Functionalized organomagnesium compounds: Synthesis and
reactivity (Paul Knochel, Andrey Gavryushin and Katja Brade).
13. Iron-Catalyzed reactions of Grignard Reagents (Gérard
Cahiez and Christophe Duplais).
14. Carbomagnesiation reactions (Kenichiro Itami and Jun-ichi
Yoshida).
15. The chemistry of organomagnesium ate complexes (Hideki
Yorimitsu and Koichiro Oshima).
16. The chemistry of magnesium carbenoids (Tsuyoshi Satoh).
17. Catalytic enantioselective conjugate addition and allylic
alkylation reactions using Grignard reagents (Fernando López,
Adriaan J. Minnaard and Ben L. Feringa).
Author Index.
Subject Index.
เกี่ยวกับผู้แต่ง
Professor Zvi Rappoport, Department of Organic Chemistry, The Hebrew University of Jerusalem, Jerusalem, Israel.
Ilan Marek is Professor of Chemistry at the Technion – Israel Institute of Technology. He was educated in France and received his Ph D thesis in 1988 from the University Pierre et Marie Curie, Paris. He has been visiting Professor at the University de Montreal (Canada); University of Strasbourg (France); University Paris-Descartes (France); California Institute of Technology (USA) and at the Ecole Nationale Superieure de Chimie de Montpellier (France). He was a member of the International Scientific Committee of the European Symposium on Organic Chemistry (ESOC), including the position of Chairman (2007-2009) and is currently the chairman of the division of organic chemistry, European Association of Chemical and Molecular Sciences (Eu Che MS).
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