The two-volume set on C-1 Building Blocks in Organic Synthesis critically reviews the state of the art of a wide variety of reactions by which one carbon atom is added to an organic molecule, forming a C-C bond. In spite of the numerous classic reactions of this kind, there has been enormous progress in recent years, especially for those reactions involving catalytic methods. Introduction of substituted methyl groups is a major challenge and only very recently the first catalysts have been discovered that enable the introduction of fluoromethyl groups in aromatics.
Зміст
1.1 Addition to Alkenes
1.1.1 Hydroformylation of Alkenes
1.1.2 Asymmetric Hydroformylation of Alkenes
1.1.3 Tandem Hydroformylation of Alkenes
1.1.4 Nonconventional Reaction Media: Hydroformylation, Carbonylation, and Hydroxycarbonylation of Alkenes
1.1.5 Hydroformylation of Alkenes: Industrial Applications
1.1.6 Carbonylation of Alkenes
1.1.7 Cyclopropanation of Alkenes with C-1
1.1.8 Addition of Carbon Dioxide to Alkenes and Other Unsaturated Hydrocarbons
1.1.9 Hydrocyanations of Alkenes
1.1.10 Stereoselective Conjugate Addition of Methyl and Cyanide
1.1.11 Enantioselective Conjugate Addition of Nitromethane
1.2 Addition to Alkynes
1.2.1 Carbonylation of Alkynes
1.3 Addition to Carbonyl Compounds and Derivatives
1.3.1 Stereoselective (Nucleophilic) Methylation of Ketones and Aldehydes
1.3.2 Cyanation of Ketones, Aldehydes, and Imines
1.3.3 Stereoselective Addition of Nitromethane
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