Polymer Syntheses, Volume I presents detailed laboratory instructions for the preparation of polymers by different functional group classes. This book provides the laboratory procedures for the preparation of polymers containing phosphorus in various oxidation states. Organized into 15 chapters, this volume begins with an overview of some selected preparative methods for carrying out the major methods of polymerization in the laboratory. This text then examines the synthesis of phosphonitrilic polymers. Other chapters consider the synthesis of peroxide and hydroperoxide free radical initiators. This book discusses as well the principles involved in the preparation of emulsion polymers, which are applicable to the preparation of polymers of a wide variety of vinyl monomers and many copolymerizations. The final chapter deals with the chemistry of organometallic and organometalloid peroxides. This book is a valuable resource for chemists involved in the designing of phosphorus polymers to meet fire retardant requirements of various products.