The C-C bond is a basic building block in chemistry and its formation is often the first step towards building more complex molecules. The direct generation of C-C bonds from C-H by cross-dehydrogenative-coupling (CDC) reactions in 2003 has presented a paradigm shift towards more efficient synthetic design, and over the last decade this has become a hot topic in Green Chemistry.
This edited book presents a summary of the latest developments in the formation of C-C bonds direct from two different C-H bonds via oxidative dehydrogenative couplings. The editor, (CJ Li, Mc Gill University) has pioneered various copper and organo-catalyzed CDC reactions within his Green Chemistry and Organic Synthesis group, and has brought together expertise from across the world to present the various CDC reactions being used today. Practicing synthetic chemists seeking to improve the efficiency of their reactions will benefit from this approach, while students and those wishing to adopt these reactions will gain a thorough understanding of the field. The conclusions presented at the end of the book will inspire all readers to the future opportunities in the field.
Mục lục
Introduction; Oxidative Heck-Type Reaction: The Fujiwara-Moritani Reaction; Copper-Catalyzed CDC Reactions; Iron Catalyzed CDC Reactions; Light-Assisted CDC Reactions; Aryl-Aryl Coupling via CDC Reactions; Asymmetric CDC Reactions; CDC Reactions without Metal; Intramolecular CDC Reactions; Synthetic Applications of CDC Reactions; Conclusions
Giới thiệu về tác giả
Peter Rudolf Seidl – Professor, Graduate Program on Technology of Chemical and Biochemical Processes, EQ/UFRJ (TPQB/EQ/UFRJ), and responsible for the establishment of the Brazilian Green Chemical School (EBQV). Thesis advisor and project coordinator in physical organic chemistry applied to chemical process areas such as petroleum, pharmaceuticals, mineral technology, etc., publishing widely in these areas and holding an international patent on the use of cashew wastes as a raw material. Former President of the Brazilian Chemical Association (ABQ) and active in the organization of meetings and workshops, such as the 1st International Conference on Chemistry of the Amazon (held shortly after Rio 92) and, more recently, the 1st Workshop on Asphaltenes Characterization and Properties held in 2009 and Biorefineries 2010 Recent Advances and New Challenges, held last November.
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