Water in Organic Synthesis is essential for the organic chemist in helping gain a thorough appreciation of the latest and most reliable available methods for using water in organic synthesis. It illustrates how water can often be a viable and green solvent in the laboratory and provides a detailed introduction to the subject: background information, evaluated methods, practical applications, industrial applications, special techniques, and an overview of the latest trends. The reference work also helps in inspiring chemists worldwide to find new approaches and techniques for the application of water in organic synthesis.
- Comprehensive overview of a rapidly progressing field
- Critical review of aqueous reactions by 47 experts
- Covering almost all types of organic reactions
- Including special techniques with water and industrial applications
- Emphasis on environmental aspects
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<p>1 Introduction<br>2 Structure and Properties of Water<br>3 Aqueous Media: Reactions of C—C Multiple Bonds<br>3.1 Asymmetric Oxidation Reactions: Sulfoxidation, Epoxidation, Dihydroxylation, and Aminohydroxylation<br>3.2 Hydrogenation of Alkenes, Alkynes, Arenes, and Hetarenes<br>3.3 Hydroformylation and Related Reactions<br>3.4 Conjugate Addition Reactions<br>3.5 Cyclopropanation Reactions<br>3.6 Metathesis Reactions<br>4 Aqueous Media: Reactions of Carbonyl and Imino Groups<br>4.1 Reduction of Carbonyl and Imino Groups<br>4.2 Alkylation, Allylation, and Benzylation of Carbonyl and Imino Groups<br>4.3 Arylation, Vinylation, and Alkynylation of Carbonyl and Imino Groups<br>4.4 Aldol Reaction<br>4.5 Mannich Reaction and Baylis–Hillman Reaction<br>5 Aqueous Media: Cyclization, Rearrangement, Substitution, Cross Coupling, Oxidation, and Other Reactions<br>5.1 Cycloaddition and Cyclization Reactions<br>5.2 Pericyclic Rearrangements: Sigmatropic, Electrocyclic, and Ene Reactions<br>5.3 Allylic and Aromatic Substitution Reactions<br>5.4 Cross-Coupling and Heck Reactions<br>5.5 Ring Opening of Epoxides and Aziridines<br>5.6 Asymmetric α-Functionalization of Carbonyl Compounds and Alkylation of Enolates<br>5.7 Oxidation of Alcohols, Allylic and Benzylic Oxidation, Oxidation of Sulfides<br>5.8 Free-Radical Reactions<br>5.9 Polymerization<br>6 Special Techniques with Water<br>6.1 Organic Synthesis ‘On Water'<br>6.2 Sub- and Supercritical Water<br>6.3 β-Cyclodextrin Chemistry in Water<br>7 Industrial Application<br>7.1 Hydroformylation<br>7.2 Industrial Applications Other than Hydroformylation<br>8 Perspective: The New World of Organic Chemistry Using Water as Solvent</p>
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