This book constitutes the refereed proceedings of the 14th International Workshop on Post-Quantum Cryptography, PQCrypto 2022, held in College Park, MD, USA, in August 14-18, 2023.The 25 full papers presented in this book were carefully reviewed and selected from 51 submissions. They are categorized in the following topical sections: code-based cryptography; group-action-based cryptography; isogenye-based cryptography; lattice-based cryptography; multivariate cryptography; quantum algorithms, cryptanalysis and models; post-quantum protocols; side channel cryptanalysis and countermeasures.