The reference work ‘Science of Synthesis: Catalytic Transformations via C-H Activation’ covers the state of the art in C-H activation chemistry. Experts in the field present the best synthetic methods including typical or general experimental procedures. As such, this two volume set can serve as both a basis for the practical application of the techniques discussed, and as an educational resource to lay the foundations for future research.
Volume 2 concerns the formation of C-C bonds by C-H activation of non-(het)arene substrates as well as C-H activation using special reagents or techniques. The formation of C-heteroatom bonds by predominantly arene C-H activation is also reviewed. For C-C bond formation, the material is subdivided into allylic, alkyl, and double C-H activation techniques, coupling using carbenes or radicals, and carbonylation or carboxylation processes.
Table des matières
<p>2.1 C—C and C—X Bond Formation by Allylic C—H Activation<br>2.2 C—C Bond Formation by Alkyl C—H Activation<br>2.3 C—C Bond Formation Using Carbenes<br>2.4 C—C Bond Formation Using Radicals<br>2.5 C—C Bond Formation by Double C—H Activation<br>2.6 C—C Bond Formation by C—H Carboxylation or Carbonylation<br>2.7 C—Hall Bond Formation by Arene C—H Activation<br>2.8 C—N Bond Formation by Arene C—H Activation Using a Palladium Catalyst<br>2.9 C—N Bond Formation by C—H Functionalization via Metal-Catalyzed Nitrene Insertion<br>2.10 C—O Bond Formation by Arene C—H Activation via Biomimetic and Organocatalytic Oxidation<br>2.11 C—O Bond Formation by Arene C—H Activation via Metal-Catalyzed Oxidation<br>2.12 C—B Bond Formation by Arene C—H Activation</p>
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