The reference work ‘Science of Synthesis: Catalytic Transformations via C-H Activation’ covers the state of the art in C-H activation chemistry. Experts in the field present the best synthetic methods including typical or general experimental procedures. As such, this two volume set can serve as both a basis for the practical application of the techniques discussed, and as an educational resource to lay the foundations for future research.
Volume 2 concerns the formation of C-C bonds by C-H activation of non-(het)arene substrates as well as C-H activation using special reagents or techniques. The formation of C-heteroatom bonds by predominantly arene C-H activation is also reviewed. For C-C bond formation, the material is subdivided into allylic, alkyl, and double C-H activation techniques, coupling using carbenes or radicals, and carbonylation or carboxylation processes.
表中的内容
2.1 C—C and C—X Bond Formation by Allylic C—H Activation
2.2 C—C Bond Formation by Alkyl C—H Activation
2.3 C—C Bond Formation Using Carbenes
2.4 C—C Bond Formation Using Radicals
2.5 C—C Bond Formation by Double C—H Activation
2.6 C—C Bond Formation by C—H Carboxylation or Carbonylation
2.7 C—Hall Bond Formation by Arene C—H Activation
2.8 C—N Bond Formation by Arene C—H Activation Using a Palladium Catalyst
2.9 C—N Bond Formation by C—H Functionalization via Metal-Catalyzed Nitrene Insertion
2.10 C—O Bond Formation by Arene C—H Activation via Biomimetic and Organocatalytic Oxidation
2.11 C—O Bond Formation by Arene C—H Activation via Metal-Catalyzed Oxidation
2.12 C—B Bond Formation by Arene C—H Activation
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